In order to accurately, reasonably, and scientifically evaluate the personnel intrinsic safety of ship construction enterprise, the evaluation of personnel intrinsic safety of ship construction enterprise is studied, and the Analytic Hierarchy Process (AHP)-Fuzzy Comprehensive Evaluation (FCE) model is constructed. The evaluation indexes of personnel intrinsic safety of ship construction enterprise are screened, and the evaluation index system of personnel intrinsic safety is determined. The personnel intrinsic safety of Shipyard H is evaluated with the AHP-FCE model, and the personnel intrinsic safety level of Shipyard H is obtained finally, which can realize the prevention of personnel safety accidents and the guarantee of personnel intrinsic safety of ship construction enterprise.